Structure and Conformational Studies of Aza‐Crown 8‐Amino‐BODIPY Derivatives: Influence of Steric Hindrance on Their Photophysical Properties

Costero, Ana M.; Betancourt-Mendiola, Lourdes; Gaviña, Pablo; Ochando, Luís E.; Gil, Salvador; Chulvi, Katherine; Peña‐Cabrera, Eduardo

doi:10.1002/ejoc.201701016

Cited by 11 publications

(3 citation statements)

References 35 publications

(32 reference statements)

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“…A coordination-based fluorescent probe using 8-amino-BODIPY for the zinc ion was reported by Peña-Cabrera and co-workers in 2017 [30]. In this study, they have synthesized several azacrown 8-amino-BODIPY derivatives and analyzed their photophysical properties.…”

Section: Metal Ions (Mercury Ions; Hg 2+ Zinc Ions; Zn 2+ )mentioning

confidence: 89%

Blue-Emitting BODIPY Dyes

Kim¹

2019

BODIPY Dyes - A Privilege Molecular Scaffold With Tunable Properties

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BODIPY which consists of a dipyrromethene complex with disubstituted boron has emerged as a superior fluorophore in various research fields. BODIPY typically shows high quantum yield with environment-insensitive fluorescence emission, sharp excitation and emission peaks, high water solubility and biocompatibility, and photostability. So far, various kinds of BODIPY derivatives have been developed and applied in not only academia such as chemistry, biochemistry, biomedical engineering, and medicine but also industries. BODIPY shows dramatic photophysical property changes upon substitution of functional groups or pi bond elongation on the main core structure. Among them, the blue-emitting BODIPY dyes with their synthesis and photophysical analysis were recently reported. In this chapter, the key information of the blue-emitting BODIPY dyes and their recent cutting-edge applications are summarized.

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Section: Metal Ions (Mercury Ions; Hg 2+ Zinc Ions; Zn 2+ )mentioning

confidence: 89%

Blue-Emitting BODIPY Dyes

Kim¹

2019

BODIPY Dyes - A Privilege Molecular Scaffold With Tunable Properties

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“…To retain the emission of the triad in the visible region of the spectrum, the third dye should be on the short-wave side of the established dyad. 69 Meso-amino substituted Bodipy constitute a synthetically variable and easily available group of uorophores, [70][71][72][73] which display absorption/ emission properties in the 400-450 nm region and which appear to be suitable for a Bodipy triad. In order to select the most appropriate dye the absorption and emission spectra of four different amino-Bodipy B1, B2, B3 and B4 were measured (Scheme 7).…”

Section: Evaluation Of the Blue-green Dyadmentioning

confidence: 99%

Fluorescent organometallic dyads and triads: establishing spatial relationships

2023

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“…To retain the emission of the triad in the visible region of the spectrum, the third dye should be on the short-wave side of the established dyad. 69 Meso-amino substituted Bodipy constitute a synthetically variable and easily available group of fluorophores, [70][71][72][73] which display absorption/emission properties in the 400 -450 nm region and which appear to be suitable for a Bodipy triad. In order to select the most appropriate dye the absorption and emission spectra of four different amino-Bodipy B1, B2, B3 and B4 were measured (scheme 7).…”

Section: Fret Studies On Green-red Nhc-gold Complexes the Reaction Of...mentioning

confidence: 99%

Fluorescent Organometallic Dyads and Triads: Establishing spatial Relationships

Plenio

Shinozaki

Popov

2022

Preprint

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FRET pairs involving up to three different Bodipy dyes are utilized to provide information on the assembly/disassembly of organometallic complexes. Azolium salts tagged with chemically robust and photostable blue or green or red fluorescent Bodipy, respectively, were synthesized and the azolium salts used to prepare metal complexes [(NHC_blue)ML], [(NHC_green)ML] and [(NHC_red)ML] (ML = Pd(allyl)Cl, IrCl(cod), RhCl(cod), AuCl, Au(NTf2), CuBr). The blue and the green Bodipy and the green and the red Bodipy, respectively, were designed to allow the formation of efficient FRET pairs with minimal cross-talk. Organometallic dyads formed from two subunits enable the transfer of excitation energy from the donor dye to the acceptor dye. The blue, green and red emission provide three information channels on the formation of complexes, which is demonstrated for alkyne or sulfur bridged digold species and for ion pairing of a red fluorescent cation and a green fluorescent anion. This approach is extended to probe an assembly of three different subunits. In such a triad, each component is tagged with either a blue, a green or a red Bodipy and the energy transfer blue green  red proves the formation of the triad. The tagging of molecular components with robust fluorophores can be a general strategy in (organometallic) chemistry to establish connectivities for intermediates in homogeneous catalysis

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Structure and Conformational Studies of Aza‐Crown 8‐Amino‐BODIPY Derivatives: Influence of Steric Hindrance on Their Photophysical Properties

Cited by 11 publications

References 35 publications

Blue-Emitting BODIPY Dyes

Blue-Emitting BODIPY Dyes

Fluorescent organometallic dyads and triads: establishing spatial relationships

Fluorescent Organometallic Dyads and Triads: Establishing spatial Relationships

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