In this paper, the authors report the structure and mechanical properties of WC-Co coatings produced on low carbon steel substrates by liquid state sintering in vacuum. Special attention is paid to the research of structure evolution during sintering and of complex carbide formation. Material structure was investigated by optical microscopy and scanning electron microscopy. The coating phase composition was researched within the temperature range of 600-1200uC using high temperature X-ray diffractometer. Brittle complex carbides appeared within the temperature range of 600-800uC. The result was confirmed by differential scanning calorimetry. Complex carbide formation increases when the carbon content is low. The results of the research were used to develop a method to suppress the formation of brittle complex carbides by changing the chemical composition of the substrate surface.