Abstract:Hydrogen atom‐donating ability of alkane is a research hotspot and has been extensively studied. In this article, the second‐order rate constants of 20 hydrogen atom transfer (HAT) reactions between aliphatic, benzylic, and allylic alkanes and alkane derivatives with CumO• in acetonitrile at 298 K were studied. The thermo‐kinetic parameter ΔG≠o(XH), bond dissociation free energy ΔGo(XH), and kinetic intrinsic resistance energy ΔG≠XH/X were determined and used to evaluate the H‐donating abilities of these subst… Show more
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