Structural, vibrational and optical properties of a new self assembled organic–inorganic nanowire crystal (C6H14N)2[BiBr5]. A Density Functional Theory approach

Synthesis of a New Chloro Antimony Complex with Pyridinium Derivative: Crystal Structure, Hirshfeld Surface Analysis, Vibrational, and Optical Properties

“…According to some studies reported in the literature [2,[27][28][29][30][31][32][33][34][35] we can propose an attempt of assignment of the observed bands Table 3.…”

“…Among these complexes, the materials based on antimony (III) are good examples of this behavior. Nowadays, these compounds have received special attention for their various physical and chemical properties such as magnetic or ferroelectric transitions, conductivity (super conductivity), electroluminescence and photo-luminescence [1,2]. In particular case of aromatic antimonate (III) chlorides, [SbCl 4 ] − anions are obtained [3,4].…”

Crystal structure, vibrational spectroscopy and optical properties of a one-dimensional organic–inorganic hybrid perovskite of [NH3CH2CH(NH3)CH2]BiCl5

“…Structurally, hybrid perovskites combine the characteristics of organic and inorganic functionalities in one molecule through non-covalent interactions. While the inorganic components contribute to semiconducting behavior and optical properties whereas the organic counterparts offer structural diversity and dynamic behavior (Bi et al, 2009;Cheng & Lin, 2010;Ouasri et al, 2012;Chen et al, 2015;Dammak et al, 2015;Abdel-Aal et al, 2017a,b;Abdel-Aal & Abdel-Rahman, 2017;Mostafa et al, 2017a,b;Mondal et al, 2017;Fredj et al, 2017;Mostafa et al, 2018;Abdel-Aal & Abdel-Rahman, 2019).…”

“…The dimensionality of OIHPs could be tuned according to (a) the chemical formula, (b) coordination geometry of the metal ion and (c) the valence of organic cation. The OIHPs could be found in different forms; 3-D of general formula AMX 3 (Cheng & Lin, 2010;Ouasri et al, 2012;Chen et al, 2015;Xing et al, 2013;Fan et al, 2018), 2-D A 2 MX 4 (Abdel-Aal et al, 2017a,b;Abdel-Aal & Abdel-Rahman, 2017;Mostafa et al, 2017a;Mondal et al, 2017;Mostafa et al, 2017b;Fredj et al, 2017;Mostafa et al, 2018;Abdel-Aal & Abdel-Rahmanet al, 2019) and 1D A 2 MX 5 (Bi et al, 2009;Ouasri et al, 2012;Dammak et al, 2015;Fredj et al, 2017), where A is organic cation, M is metal ion, X is halide Cl, Br or I. The structure tunability can be achieved by changing A, M and X.…”

“…Its structure has the [BiX 6 ] 4À octahedra connected by edge-sharing surrounded by organic cations, which allows bulk assemblies of 1D quantum confined materials to form. The unique structure displays interesting photophysical properties (Bi et al, 2009;Ouasri et al, 2012;Dammak et al, 2015;Fredj et al, 2017). In this work, the crystal structure of propane-1,2diammonium penta-chlorobismuthate, [NH 3 CH 2 CH(NH 3 )-CH 3 ]BiCl 5 is presented.…”