Structural transformation mediated by o-, m-, and p-phthalates from two to three dimensions for manganese/phthalate/4,4′-bpy complexes (4,4′-bpy = 4,4′-bipyridine)

Structural Trends in Coordination Polymers Containing Perfluorinated Dicarboxylates and 4,4′‐Bipyridine

“…These materials also tend to involve multi-dentate coordination through the carboxylate groups to form double chains or dimeric units, which is not seen in 1-4. When comparing the specific structures to previous reports with their non-fluorinated analogs and 4,4-bpy, we find that compound 2 is analogous to a previously reported phase [26]. To our knowledge this is the first hybrid framework material where the perfluorinated carboxylate forms a similar structure to that of its non-fluorinated analog.…”

Crystal structure of tetraaqua-(4,4′-diamino-1,1′-biphenyl-2,2′-disulfonato-κN)(4,4′-bipyridyl-κN)zinc(II) trihydrate, C22H32N4O13S2Zn

“…So far, most of these materials are constructed by various rigid organic bidentate ligands containing pyridine rings, dicarboxylate, phosphonate, and sulfonate as spacers and metal cores as connectors [6][7][8][9][10]. Organic bridging ligands not only bind several metal centers of speci c coordination geometry but also can transmit the magnetic interactions.…”

Crystal structure of diaqua-bis(1,10-phenanthroline)- manganese(II) thiophene-2,5-dicarboxylate octahydrate, [Mn(H2O)2(C12H8N2)2][C6H2O4S] · 8H2O

“…In as pontaneous assembly process, the structural information stored in the organic ligands is read by the metal ion through its coordination [4]. The choice of appropriate organic ligands and metal is important to construct distinct architectures, from which corresponding properties are derived [5]. The family of thiophenecarboxylates and other linkers with electron delocalization is prone to transmit magnetic interactions in addition to propagating the network [6][7][8][9].…”

“…In as pontaneous assembly process, the structural information stored in the organic ligands is read by the metal ion through its coordination [4]. The choice of appropriate organic ligands and metal is important to construct distinct architectures, from which corresponding properties are derived [5]. …”