Structural study, spectroscopic characterization, DFT calculations and electrical properties of manganese (II) organic-inorganic hybrid material (C8H14N2)2[MnCl4(H2O)2]Cl2

Structural Study, Spectroscopic Characterization and Evaluation of the Antimicrobial Behavior of a New Fe (III) Organic‐Inorganic Hybrid Material: (C8H14N2)4[(FeCl6)(FeCl4)]Cl4

“…The υ(C−C−N), υ(C=C−C) rings stretching mode could be assigned at 1091 and 901 cm −1 . These data are in agreement with other compound treated by similar cations [38,39,47] . A weak band appears at 564 cm −1 , assigned to the δ(Fe−Cl) mode of the anionic group [48,49] …”

“…Furthermore, the C−C distances ranging from 1.375 (4) Å to 1.514 (4) Å, while the (C−C−C) angles varying from 119.2 (2)° to 121.7 (2)°. These results are quite comparable to those observed in other compounds containing the same organic groups [38–40] . Table S2 shown in the supporting information, demonstrates the selected bond distances and angles.…”

“…These results are quite comparable to those observed in other compounds containing the same organic groups. [38][39][40] Table S2 shown in the supporting information, demonstrates the selected bond distances and angles. No π-π stacking occurs in this structure.…”

“…These data are in agreement with other compound treated by similar cations. [38,39,47] A weak band appears at 564 cm À 1 , assigned to the δ(FeÀ Cl) mode of the anionic group. [48,49]…”

A green and efficient process for the stepwise extraction of Cu, Ni, Co, Mn, and Li from hazardous waste with a novel solvent extraction system of D2EHPA-NNPA

“…Additionally, a more intuitive verification of the above binding energy calculations was performed by using molecular electrostatic potential (MEP) analysis, which offers insights into the chemical reactivity of NNPA with metal ions. 37,38 Fig. 4 shows the surface charge distribution of the NNPA-metal complex, where blue areas represent the positive electrostatic potential region and green areas represent the zero potential region.…”