“…The peak observed at 1639 cm −1 may correspond to the ring-stretching of mannose or galactose [44], or to the aromatic \ \C_C\ \ groups of the humic substances [42,45]. The two peaks observed at 1425 and 1384 cm −1 could have been caused by the\ \OH group of phenol, symmetrical stretching of the\ \COO group of humic substances [42,46], or to the \ \CH 2 \ \ bending of saccharides [47][48][49][50], whereas the peak at 1139 cm − 1 may have been caused by either the C\ \O\ \C and C\ \O groups of carbohydrates [44,51] or the aliphatic structures of humic substances with high levels of oxygen-rich functional groups [45]. Adsorption peaks ranging from 1000 to 800 cm − 1 were attributed to pyranoidal ring structure vibration of saccharides [49][50], and the adsorption peak at 644 cm − 1 corresponded to the stretching of alkyl-halides [51].…”