1998
DOI: 10.1080/10426509808045499
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Structural Studies of a Novel Heterocyclic Phosphorane

Abstract: Reaction of 2,2,6-trimethylthiochroman-3,4-dione with an excess of methylenetriphenylphosphorane yields the stabilised ylide (4) by way of an a-ketol rearrangement. X-Ray crystallography indicates that (4) exists as the (a-isomer and provides supporting evidence for an enolate structure.

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