Structural stabilities of sulfonated manganese tetramesitylporphyrin and its β-brominated analogue toward NaOCl, H2O2 and (CH3)3COOH

Bromination of porphyrins (Review)

“…of N-bromosuccinimide in boiling chloroform [67]. The authors of [49,52,53,57,92] also reached their own conclusion in favour of N-bromosuccinimide during the production of octabromotetraarylporphyrinates [93]. Here such parameters as the solvent, rate of addition of the reagents, and reaction time were varied.…”

Peroxidase-Like Catalytic Activity of Aqueous- and Immobilized-Mn3+-octabromo-porphyrins on Ion-Exchange Resin Supplied as Mimetic of Horseradish Peroxidase

“…[4][5][6][7] The authors also have reported that M-Ps immobilized ion-exchange-resins or -glass-beads have a practical use in the flow injection analyses as a solid mimetic of catalase or HRP. [8][9][10][11][12] However, those solid mimetics are not practically applicable to the batch method because of troublesome procedures required for the separation and the like.Recently, metal-octabromo-porphyrins (M-OBPs), which are resistant to oxidation, have been developed and elucidated their physical properties [13][14][15][16][17] as well as enzyme-like catalytic activities such as P450-, 18) superoxide dismutase- 19) and peroxidase-like catalytic activities on an organic-hydroperoxide. 20) In the present study, we examined the HRPlike activities of six different ionic manganese-porphyrins (Mn-Ps) and Mn-OBPs (see Fig.…”

“…Recently, metal-octabromo-porphyrins (M-OBPs), which are resistant to oxidation, have been developed and elucidated their physical properties [13][14][15][16][17] as well as enzyme-like catalytic activities such as P450-, 18) superoxide dismutase- 19) and peroxidase-like catalytic activities on an organic-hydroperoxide. 20) In the present study, we examined the HRPlike activities of six different ionic manganese-porphyrins (Mn-Ps) and Mn-OBPs (see Fig.…”