Structural phase transition driven dielectric and optical properties with reduction in band gap in Sr²⁺ modified BaTiO₃ ceramics

Abstract

Ferroelectric materials with crystal symmetry transition from single phase to multiphase coexistence exhibit anomalous photosensitive properties. The optical properties (optical band gap and photosensitive) found on non-centrosymmetric and centrosymmetric systems achieved research interest because of their interesting behaviour. In this regard, the lead-free polycrystalline Ba1-xSrxTiO3 (0 ≤x≤0.3) has been synthesized to explore its crystal structure, dielectric, light absorption, and photocurrent sensing properties for various applications. Both experimental and theoretical studies on Ba1-xSrxTiO3 (0 ≤x≤0.3) ceramics confirm the crystal symmetry transition with the reduction of band gap as compared to pristine BaTiO3. This crystal symmetry transition plays an important role in varying the various physical properties as it involves the transition from the polar phase to the non-polar phase. The optical band gap has been estimated experimentally by the Tauc plot method and found that there is a small variation of energy band gap from 3.615 eV to 3.212 eV with Sr substitution. The highest dielectric constant was found to be 5327 on Ba0.76Sr0.24TiO3 at lower frequency after that for further increase in Sr concentration the dielectric constant decreases because of the introduction of the non-polar phase. A strong correlation between crystal structure and physical properties (dielectric, optical, etc.) has been observed. The photocurrent of the samples is significant which reveals that the sample is influenced by the photons. In a nutshell, the present study deepens the understanding of the correlation between crystal structure and various physical properties of Ba1-xSrxTiO3 and, hence provides an idea of required design parameters to construct a ferroelectric system for better photosensitive nature suitable for device applications.