Structural investigation of SnO–B2O3 glasses by solid-state NMR and X-ray photoelectron spectroscopy

Hayashi, Akitoshi; Nakai, Miyuki; Tatsumisago, Masahiro; Minami, Tsutomu; Himei, Yusuke; Miura, Yoshio; Katada, Motomi

doi:10.1016/s0022-3093(02)01169-9

Cited by 43 publications

(54 citation statements)

References 27 publications

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“…However, they concluded that the reaction (2) is not feasible because of any clear evidence of Li 2 O by 6 Li MAS-NMR measurements. We consider the product of the reactions described above.…”

Section: Discussionmentioning

confidence: 99%

“…Actually, SnO-based multicomponent glasses prepared using the melt quenching method have been studied extensively as candidates for use as negative electrodes with larger capacity than a carbon electrode in commercially available lithium ion batteries [1][2][3][4]. We have prepared various SnO-based binary glasses in SnO-B 2 O 3 , SnO-BPO 4 , and SnO-P 2 O 5 systems using melt quenching and mechanical milling techniques [5][6][7][8][9]. Electrochemical properties of these glasses, when used as a working electrode, were examined in an electrochemical cell using a conventional liquid electrolyte.…”

Section: Introductionmentioning

confidence: 99%

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Electrochemical performance and structural change during charge–discharge reaction of SnO–P2O5 glassy electrodes in rechargeable lithium batteries

Konishi

Hayashi

Tadanaga

et al. 2008

Journal of Non-Crystalline Solids

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Section: Discussionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Electrochemical performance and structural change during charge–discharge reaction of SnO–P2O5 glassy electrodes in rechargeable lithium batteries

Konishi

Hayashi

Tadanaga

et al. 2008

Journal of Non-Crystalline Solids

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“…We have analyzed the structure of the SnO-B 2 O 3 glasses by several spectroscopic techniques such as Raman, NMR, and XPS [9]. Glass transition temperatures, activation energies for viscous flow, and specific capacity of the glasses proved to be influenced by the glass structure, namely by four-coordinated borons and non-bridging oxygens in the glass network [9][10][11]. From the structural point of view, binary phosphate glasses are an interesting glass matrix as the SnO-based anode materials for lithium secondary batteries.…”

Section: Introductionmentioning

confidence: 99%

Preparation and characterization of SnO–P2O5 glasses as anode materials for lithium secondary batteries

Hayashi

Konishi

Tadanaga

et al. 2004

Journal of Non-Crystalline Solids

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“…At 2 tetrahedra is nx/(12x), a relation obeyed at nx smaller than y25% by alkali 405 and large alkaline earth (Sr, Ba) 404 398 In contrast, with PbO ( Fig. 7), N 4 behaves closer to ideal at low x.…”

Section: Bonding In Crystalline Compoundsmentioning

confidence: 95%

Review of Bi₂O₃ based glasses for electronics and related applications

Maeder

2013

International Materials Reviews

146

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The present work critically reviews the scientific and patent literature on low melting bismuth based oxide glass frits in materials for electronics, sensors and related applications such as sealing glasses, solar cells, architectural and automotive glass, the main motivation being to replace lead based materials by environmentally more benign ones. Due to similar glass forming properties of Bi and Pb, Bi based glasses are the closest 'drop-in' alternative for lead bearing formulations, and are therefore actually replacing them in many applications, helped also by previous experience with Bi containing materials in thick film technology and component metallisations. The outstanding issues are discussed, e.g. matching the lowest processing temperatures achieved by the classical lead based glasses without sacrificing durability and stability, as well as stability versus chemical reduction. Finally, consideration is also given to special 'heavy' glasses (often containing Bi and Pb together) that are useful in fields such as optics, superconductors and nuclear technology, as well as to specific Bi 2 O 3 containing crystalline compounds.Keywords: Glasses, Bismuth, Bi 2 O 3 , Electronics, Optics, Thick film technology, Sensors Introduction Low melting glasses in electronics and other applicationsAs for ceramics, inorganic glasses, glass-ceramic and glaze materials have long gone beyond their traditional uses to address a wide array of modern technological challenges, Owing to performance and cost criteria, most standard glasses have relatively high softening points. However, there are many technological applications where a low softening temperature is required, in order to lower energy expenditure, avoid damaging devices in contact with the glass during processing or ensure compatibility with other materials:(i) hermetic sealing of packages, lamps, electrical feedthroughs and semiconductor devices 13,14,16,17,19,44,45 (ii) hermetic sealing and mechanical attachment of sensors 23,27 ( Fig. 1) (iii) encapsulation of semiconductor devices 29,30 (iv) overglazing of automotive, packaging and architectural glass 33,34,[46][47][48] (v) photovoltaic (PV) solar cell technology -conductors and contacts 42,43,[49][50][51][52][53] (vi) enamelling of aluminium in architecture and home appliances 35,[54][55][56][57][58] (vii) thick film (TF) electronics and other devices 21,22,24,25,27,59 (Fig. 1, the section on 'PbO in low melting frits and TF technology'); especially, special low firing compositions for fabrication of circuits and sensors on glass or metals. 1,28,[66][67][68][69][70][71][72] For these applications, glasses are often formulated as frits (e.g. finely divided powder), which may be applied, dispersed in a suitable medium, onto a substrate by various methods such as slip casting, screen printing, roller/curtain coating, spraying, dispensing and electrophoresis, or as preforms for sealing. Classically, the aforementioned applications have to a great extent used lead based glasses, which have a rather unique combinat...

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Structural investigation of SnO–B2O3 glasses by solid-state NMR and X-ray photoelectron spectroscopy

Cited by 43 publications

References 27 publications

Electrochemical performance and structural change during charge–discharge reaction of SnO–P2O5 glassy electrodes in rechargeable lithium batteries

Electrochemical performance and structural change during charge–discharge reaction of SnO–P2O5 glassy electrodes in rechargeable lithium batteries

Preparation and characterization of SnO–P2O5 glasses as anode materials for lithium secondary batteries

Review of Bi₂O₃ based glasses for electronics and related applications

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Structural investigation of SnO–B2O3 glasses by solid-state NMR and X-ray photoelectron spectroscopy

Cited by 43 publications

References 27 publications

Electrochemical performance and structural change during charge–discharge reaction of SnO–P2O5 glassy electrodes in rechargeable lithium batteries

Electrochemical performance and structural change during charge–discharge reaction of SnO–P2O5 glassy electrodes in rechargeable lithium batteries

Preparation and characterization of SnO–P2O5 glasses as anode materials for lithium secondary batteries

Review of Bi2O3 based glasses for electronics and related applications

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Product

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Review of Bi₂O₃ based glasses for electronics and related applications