Structural features of complex hydrochemical systems

Abstract

The set of non-conservative hydrochemical parameters is considered as a complex system, which displays collective behavior. It is found that the collective behavior is described by the power relation between the time variability (the standard deviations) and the average concentrations of different hydrochemical parameters in the scale range 100 – 0:0001 mg/kg. The exponent can be 0:7 – 0:9. Power law scaling is the mathematical expression of self similarity and fractality. The complex systems of nonconservative chemical parameters have a structure that can be characterized by exponent, normalization coefficient, standard error, correlation coefficient, and by sharp deviations of the individual parameters from the regression line and from the most probable average and standard deviation values, if any. It is shown with specific examples that changes in the hydrochemical systems structure are the result of the manifestation of biogeochemical processes and the dynamics of water. Regression analysis of collective behavior of complex hydrochemical systems is one of the examples of the use of modern information technologies based on the methods of system analysis.