Abstract:New bromothallate(III) complexes have been synthesized using eleven organoammonium cations related to others employed previously. The crystal structure determinations of eight of these have been performed. The diethylenetriammonium cation yields the first compound containing [TlBr 6 ] 3À as the only anionic species, while the N,N,N',N'',N''-pentamethyldiethylenetriammonium cation gave a mixed salt containing discrete [TlBr 4 ] À and Br À ions, in which the [TlBr 4 ] À unit does not participate in hydrogen bond… Show more
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