Structural diversity in four Zn(II)/Cd(II) coordination polymers tuned by flexible pentacarboxylate and N-donor coligands: Photocatalysts for enhanced degradation of dyes

Construction of Novel Coordination Polymers Based on Pyrazole Carboxylic Acid and Doping for Enhancing the Photocatalytic Property Under Visible Light

“…With an increase in the reaction time, the compounds with m / z = 227 and 141 appeared, which were generated due to degradation of intermediates ( m / z = 242). The possible degradation pathways are shown in Figure S18 based on previous reports and intermediates detected. − …”

Preparation of Novel Cu/Cu2O Composite Thin Films by Pulse Deposition Method and Their Enhanced Photocatalytic Performance for Methylene Blue

“…Then through deamination, oxidation and other processes occur to obtain intermediate products J (m/z 184) and K (m/z 155). [54][55][56][57] Finally, intermediates L, J, and K can be further oxidized and decomposed into CO 2 , H 2 O and some substances with lower molecular weights. Possible degradation pathways of MB by sample S6 under visible light irradiation are shown in Fig.…”

Three novel coordination polymers as bifunctional materials for the photocatalytic degradation of dyes and the oxygen evolution reaction in alkaline solutions

“…For instance, four coordination polymers synthesized by Wang et al were applied to the UV photocatalysis degradation of various dyes, among which the coordination polymer with the best performance could degrade 91.33% MB, 74.86% MO, 26.10% CR, 61.29% AO, and 17.25% ACB dyes within 100 min. 13 Shi et al 22 synthesized two Ag coordination polymers and evaluated their photocatalytic performance against MB, Rh-B, and MO under UV light, and the results showed that one of the Ag complexes was able to undergo 90.24% and 93.56% reaction rates with MB and Rh-B within 100 min, respectively. However, most CPs/MOFs photocatalysts have a limited range of applications to dye types, and many catalysts only exhibit catalytic performance for one or two kinds of dyes, which greatly limits the application prospects of CPs/MOFs in the field of photocatalytic degradation.…”

“…12 The photocatalytic reaction is a reaction system formed by the oxidation and reduction of photogenerated electrons and holes on the surface of the catalyst, which requires the photocatalytic materials to have an appropriate electronic band structure and good stability. 13 Among the many photocatalysts, coordination polymers (CPs)/metal-organic framework materials (MOFs) can be regarded as the most effective and practical. [14][15][16] By selecting specific ligands and suitable metal centers, functional framework materials with ideal structures can be rationally designed.…”