Structural, dielectric and magnetic properties of Pr substituted Bi1−xPrxFeO3 (0≤x≤0.15) multiferroic compounds

Kumar, Neeraj; Panwar, Neeraj; Gahtori, Bhasker; Singh, Neelam; Kishan, H.; Awana, V. P. S.

doi:10.1016/j.jallcom.2010.04.095

Cited by 83 publications

(37 citation statements)

References 24 publications

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“…Ion doping at Bi or Fe sites destroys the modulated structure and leads to the weak ferromagnetic ordering. No obvious hysteresis loop is observed in the case of BPF ceramic, similar to previously reported results for Pr-substituted samples [22,25]. …”

Section: Resultssupporting

confidence: 91%

“…The remnant polarization P r and coercive field E c are 0.11 μC/cm 2 and 5.42 kV/cm for BPFT-10, and 0.29 μC/cm 2 and 13.67 kV/cm for BPFT-5, respectively. The P r value of BPFT-5 is similar to those reported for BiFe 0.9 Ti 0.05 O 3 and Bi 0.85 Pr 0.15 FeO 3 [22][23]. The high P r value of BPFT-10 relative to that of BFT indicates that Pr doping improves the ferroelectric performance.…”

Section: Introductionsupporting

confidence: 78%

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Structural and multiferroic properties of Pr and Ti co-doped BiFeO 3 ceramics

Wang

Jiao

et al. 2016

Ceramics International

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Section: Resultssupporting

confidence: 91%

Section: Introductionsupporting

confidence: 78%

Structural and multiferroic properties of Pr and Ti co-doped BiFeO 3 ceramics

Wang

Jiao

et al. 2016

Ceramics International

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“…The PbZrO 3 -like structure (Pbam space group) has already 40 atoms in the unit cell. The same method of the supercell was used in [34,44]. The supercells of BiFeO 3 of aforementioned structures are presented in Fig.…”

Section: Methods Of Calculationsmentioning

confidence: 99%

“…Experimental studies of partial substitution of Bi 3? by Pr rare-earth ions in BiFeO 3 show also a large diversity in crystal phases [34,35]. Temperature-induced structural and magnetic phase transition in disordered Bi 1-x Nd x FeO 3 (0 \ x \ 0.1625) is an object of the recent published study by Xu et al [36].…”

Section: Introductionmentioning

confidence: 99%

First-principles study of structural, electronic, and ferroelectric properties of rare-earth-doped BiFeO3

Pugaczowa‐Michalska

Kaczkowski

2015

J Mater Sci

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We study the effect of the light rare earth ions La, Ce, Pr, and Nd on electronic structure, structural properties, magnetic states, and ferroelectric properties of BiFeO 3 using density functional theory within GGA ? U method. The supercell of 40 atoms is considered for four phases: R3c, Pnma, Pn2 1 a, Pbam. We show that, among potential phases, the R3c-G structure of BiFeO 3 where one Bi substituted by one of the studied rare-earth elements has the minimal total energy. We predict the values of spontaneous electric polarization in RE-doped BiFeO 3 to be above 80 lC cm -2 and a non-zero values of the magnetic moments in RE-doped BiFeO 3 for R3c-G phase of the studied systems. Upon introduction of a rare-earth ion to a Bi site, the total magnetic moments are 0 l B , 0.99, 1.99, and 2.98 l B f.u. -1 for La, Ce, Pr, and Nd substitution, respectively. The results of total energy calculations show that the Pn2 1 a and Pnma phases of the BiFeO 3 with Ce or Pr substitution of Bi occur on the same energy scale. This close energy scale suggests a coexistence of these phases beyond T = 0 K or under other conditions.

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“…Because of room-temperature coupling between ferroelectric and magnetic order parameters, it brings forth a novel phenomenon known as magnetoelectric effect (ME), in which polarization can be tuned by magnetic field and vice versa. This coupling provides an additional opportunity for the design of magnetoelectric and spintronic devices [2][3][4]. Multiferroic materials have gained tremendous attention on account of their potential applications in various fields, such as bubble memory device, microwave, satellite communication, audio-video, digital recording [4,5], sensor, multiple state memory element, electro-ferromagnetic resonance  device [6], thin film capacitor, non-volatile memory [7], optoelectronics, solar energy device [4], highdensity ferroelectric magnetic random access memory [8], and permanent magnet [9].…”

Section: Introductionmentioning

confidence: 99%

Structural, magnetic and dielectric properties of nano-crystalline Ni-doped BiFeO3 ceramics formulated by self-propagating high-temperature synthesis

Chaudhari

Mahajan²,

Jagtap

et al. 2013

J Adv Ceram

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Ni-doped BiFeO 3 powders with the composition BiFe 1x Ni x O 3 (x = 0.05, 0.1 and 0.15) were prepared by a self-propagating high-temperature synthesis (SHS), using metal nitrates as oxidizers and glycine as fuel. The X-ray diffraction (XRD) patterns depict that Ni-doped BiFeO 3 ceramics crystallize in a rhombhohedral phase. The scanning electron micrographs of Ni-doped BiFeO 3 ceramics show a dense morphology with interconnected structure. It is found that, the room-temperature magnetization measurements in Ni-incorporated

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Structural, dielectric and magnetic properties of Pr substituted Bi1−xPrxFeO3 (0≤x≤0.15) multiferroic compounds

Cited by 83 publications

References 24 publications

Structural and multiferroic properties of Pr and Ti co-doped BiFeO 3 ceramics

Structural and multiferroic properties of Pr and Ti co-doped BiFeO 3 ceramics

First-principles study of structural, electronic, and ferroelectric properties of rare-earth-doped BiFeO3

Structural, magnetic and dielectric properties of nano-crystalline Ni-doped BiFeO3 ceramics formulated by self-propagating high-temperature synthesis

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