2016
DOI: 10.1007/s00339-016-0512-y
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Structural defects and photoluminescence studies of sol–gel prepared ZnO and Al-doped ZnO films

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Cited by 22 publications
(4 citation statements)
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“…Moreover, ZnO is available in large scale, chemically stable and eco‐friendly. At room temperature, the ZnO PL spectrum typically exhibits one emission peak in the ultraviolet (UV) region due to free exciton recombination and a low intensity broad emission in the visible range, associated to point defect states transitions, such as vacancies (V o and V Zn ), interstitials (O i and Zn i ) and antisites (O Zn and Zn O ) . Experimental works, theoretical studies and simulations linking defects energy level and formation energy led to some arguable hypothesis with no consensus about their origin.…”
Section: Figurementioning
confidence: 99%
See 1 more Smart Citation
“…Moreover, ZnO is available in large scale, chemically stable and eco‐friendly. At room temperature, the ZnO PL spectrum typically exhibits one emission peak in the ultraviolet (UV) region due to free exciton recombination and a low intensity broad emission in the visible range, associated to point defect states transitions, such as vacancies (V o and V Zn ), interstitials (O i and Zn i ) and antisites (O Zn and Zn O ) . Experimental works, theoretical studies and simulations linking defects energy level and formation energy led to some arguable hypothesis with no consensus about their origin.…”
Section: Figurementioning
confidence: 99%
“…Experimental works, theoretical studies and simulations linking defects energy level and formation energy led to some arguable hypothesis with no consensus about their origin. Nonetheless, the importance of its use as emissive layer (EML) for white light generation was recognized and LEDs were built having ZnO films deposited by low‐pressure thermal evaporation . Recently, polymer/inorganic hybrid LED having ZnO nanoparticles and nanorods, Fe 3 O 4 and TiO 2 , for example, were obtained, because of their enhanced optical and electrical properties in comparison to pure polymer system …”
Section: Figurementioning
confidence: 99%
“…A Tabela 2 mostra o posicionamento e as origens propostas para a fotoluminescência do ZnO. [26][27][28].…”
Section: Emissão Dos Defeitos Do Azounclassified
“…Figura 66 mostra o espectro de fotoluminescência do AZO disperso em clorofórmio, excitado em 320 nm com auxílio de um filtro de 360 nm. Podem-se observar duas bandas de emissão com picos em 377 nm, que envolvem transições entre as bandas de condução e de valência do AZO (near band edge -NBE), e 580nm, que está relacionado à emissão devido à existência de defeitos[28]. Além disso, notou-se que a intensidade de emissão na região do UV foi quase oito vezes maior que a intensidade de emissão na região do visível.…”
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