Structural characterization of 3':2-[2',4'-C2B5H6][1,8,5,6-(.eta.-C5H5)2Co2C2B5H6]: a coupled-cage cobaltacarborane containing a boron-boron linkage

Micciche, Robert P.; Plotkin, Jeffrey S.; Sneddon, Larry G.

doi:10.1021/ic00154a014

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Mixed Borane Clusters2

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1983

2001

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Cited by 12 publications

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“…This complex has a linked skeleton of two carboranes, among which one has two metals as vertexes. 242 The generalized electron-counting rule when applied to this structure suggests an electron pair count of 34 (m ) 4, n ) 26, o ) 2, p ) 2). This is achieved by the contribution of various fragments (10 BH groups, 14 CH groups, and 2 cobalt atoms) which make up the cluster.…”

Section: Mixed Borane Clustersmentioning

confidence: 97%

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Electronic Requirements for Macropolyhedral Boranes

2001

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before joining Princeton University in 1973 for his Ph.D. degree under the supervision of Professor Paul von Rague ´Schleyer. During his years at Princeton, Jemmis spent a semester at the University of Munich (fall 1974) and two years at the University of Erlangen-Nurnberg (1976−77). After a two-year postdoctoral fellowship at Cornell with Prof. Roald Hoffmann, Jemmis returned to India in 1980 as a lecturer at the

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Section: Mixed Borane Clustersmentioning

confidence: 97%

“…[(C 2 B 5 H 6 )(Cp 2 Co 2 C 2 B 5 H 6 )] ( 105 ). This complex has a linked skeleton of two carboranes, among which one has two metals as vertexes . The generalized electron-counting rule when applied to this structure suggests an electron pair count of 34 ( m = 4, n = 26, o = 2, p = 2).…”

Section: Mixed Borane Clustersmentioning

confidence: 99%