“…The intensity of this peak increased slightly after ion irradiation, which was insignificant for structural modifications. The prominent peaks observed at 35.35°, 39.44°and 53.73°are attributed to (0 0 2), (1 0 0) and (1 0 3) respectively, these peaks attribute the formation of ZnS nanoparticles and Zn blende structure [3,21]. The shift of the absorption peak towards longer wavelength was observed due to the formation of conjugated system of bonds after ion irradiation [22][23][24].…”