Structural and photophysical studies of phenanthrene adducts involving C6F5HgCl and [o-C6F4Hg]3

Abstract

Both pentafluorophenylmercury chloride and trimeric perfluoro-ortho-phenylene mercury interact with phenanthrene to form phosphorescent adducts which exhibit extended binary stacks in the solid state.

Organometallic Polymers Assembled from Cation–π Interactions: Use of Ferrocene as a Ditopic Linker Within the Homologous Series [{(Me3Si)2NM}2⋅(Cp2Fe)]∞ (M=Na, K, Rb, Cs; Cp=cyclopentadienyl)

“…Future work will focus on the photophysical and magnetic properties of such directionally ordered materials. [121] Our calculations indicate that the strength of solvation by both ferrocene and toluene increases in the sequence Li < Na < K. However, this pattern is governed by the ability of the aromatic systems to enter the coordination sphere of the metals rather than representing the relative binding energies for simple cation-p contacts. These results demonstrate the importance of accurately modeling potential steric influences in order to obtain meaningful energetic information for cation-p interactions.…”

Effect of a polyamine biosynthesis inhibitor on the quality of grape and red wine

“…Nevertheless, the solid‐state IR and crystallographic studies indicate that participation in cation–π interactions does have noticeable effects on the bonding within the metallocene. Future work will focus on the photophysical and magnetic properties of such directionally ordered materials 121…”

Arene‐Sandwiched Silver(I) Pyrazolates

“…[15,16,28,29] The {(1)(Mes)} unit sits on a threefold rotation axis. The 1-Mes-1-Mes planes are separated by 3.32, 3.19, and 3.32 which indicates relatively tight contacts.…”