O 7 nanophosphors were synthesized via a facile sol-gel process. The samples were characterized by the inductively coupled plasma atomic emission spectrometer (ICP-AES), X-ray diffraction (XRD), transmission electron microscopy (TEM), and infrared-to-visible upconversion (UC) luminescence spectra. XRD analysis showed that the crystallization temperature of pyrochore-type Y 2 Ti 2 O 7 was reduced due to the flux effect of Li + ions, whereas TEM measurements confirmed that the particles size of (Y 0.815 Er 0.01 Yb 0.075 Li 0.10 ) 2 Ti 2 O 7 was about 30-40 nm when calcining at 800°C for 1.0 h. The calcining temperature and Li + ion concentration dependence on UC luminescence spectra were investigated. It was found that, when incorporating 10.0 mol% Li + ion, the UC red and green emission intensity was drastically increased by a factor of 18.6 and 8.3, respectively. The enhancement of UC emission may be mainly attributed to the modification of local symmetry around Er 3+ ions by tridoping Li + ions. And also, the pump power dependence of the emission intensity was investigated to understand the fundamental UC mechanism.A. Srivastava-contributing editor Manuscript No. 31924.