Structural and Optical Characterization of a New Tetra- and Hexa-Coordinated Cd-Based Hybrid Compound with White Light Emission
Imen Sayer,
Rawia Msalmi,
Edoardo Mosconi
et al.
Abstract:The present paper deals with a new two-in-one zero-dimensional (0D) organic–inorganic hybrid compound namely (C6H10N2)4[CdBr6][CdBr4]2. This molecular crystal structure contains isolated CdBr4 tetrahedra and CdBr6 octahedra. The optical characterization by UV–Vis–NIR spectroscopy shows that the (C6H10N2)4[CdBr6][CdBr4]2 exhibits a large gap energy of 4.97 eV. Under UV excitation, this hybrid material shows a bright cold white light emission (WLE) at room temperature. The photoluminescence (PL) analysis suggest… Show more
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