2013
DOI: 10.1016/j.jmmm.2013.02.038
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Structural and magnetic properties of Sn–Zn doped BaCo2Z-type hexaferrite powders prepared by citrate precursor method

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Cited by 33 publications
(11 citation statements)
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“…With the increase of SnO 2 content, the majority of peaks were related to Co 2 Z-type phase with a minor Co 2 W-type phase. The main reason led to the appearance of Co 2 W phase was due to that some Sn 4 þ ions might enter into the crystal lattice and substitute the major Fe 3 þ ions [11]. The surplus Fe 3 þ ions induced the formation of Co 2 W-type phase, which had a higher ratio of n n (Fe )/ (M ) 3 2 + + (M ¼Ba, Co) than that of Co 2 Z-type phase.…”
Section: Methodsmentioning
confidence: 99%
“…With the increase of SnO 2 content, the majority of peaks were related to Co 2 Z-type phase with a minor Co 2 W-type phase. The main reason led to the appearance of Co 2 W phase was due to that some Sn 4 þ ions might enter into the crystal lattice and substitute the major Fe 3 þ ions [11]. The surplus Fe 3 þ ions induced the formation of Co 2 W-type phase, which had a higher ratio of n n (Fe )/ (M ) 3 2 + + (M ¼Ba, Co) than that of Co 2 Z-type phase.…”
Section: Methodsmentioning
confidence: 99%
“…e preferred site for Cu 2+ ion is the tetrahedral site, while that for the Mn 2+ ion is the octahedral site [52]. e Zn 2+ ion generally prefers to occupy 4f IV tetrahedral site, with some tendency to enter the 4f VI octahedral site due to the large ionic diameter (0.74Å) [53]. e saturation magnetization M s for the sample with x � 0.0 was found to be 45 emu/g, which is close to the value of 46 emu/g reported for Cu 2 Z hexaferrite [48].…”
Section: Isothermal Magnetizationmentioning
confidence: 99%
“…If the complexion transition propagated faster than the growing grains, then all grains would eventually have high mobility boundaries. However, because the boundaries around the distant grains remain in a higher energy complexion, the rate of propagation must be low [36,37]. Selectedarea diffraction (SAED) indicates that the ZnO nanoparticles either without or with additives were well crystallized with small average particle sizes.…”
Section: (D)mentioning
confidence: 99%