Structural and electronic influences on phosphite basicity and its application to heterogeneous and homogeneous catalysis

Abstract

The mechanism of isomerization of and n'^-3-methylene-4vinyldihydrofuran-2(3H)-one complexes of Fe(0). Note; R groups on compounds succeeding ^left off for clarity. Scheme 2. 26 The mechanism for the isomerization of 1-butene using acidified Ni(P(0Et)3)4 Scheme 3. 39 Decomposition of abound metal alkyl cyanide species to form alkyl nitriles Scheme 4. 54 Attachment of metal carbonyl compounds to derivatized silica gel. Scheme 5. 68 The synthesis of meso-2,4-dimethyl-1,5-dibromopentane Scheme 6. 92