It is shown that C60 single crystals can be polymerized under
relatively modest pressure-temperature conditions. The resulting
single crystals exhibit long-range order and they are made up of 12
orientation variants. The structure is orthorhombic with a short
intermolecular distance along the chains (9.14 Å), characteristic of
covalent bonding. We propose a structural mechanism for the
polymerization of fullerene-based compounds; it involves a shift of
one of the (111) cubic planes together with a shortening of the (111)
spacing. The configuration of the polymer chains presents interesting
relations with that found in the A1C60 polymer compounds.