Structural and computational analyses of a 2-propanolammonium-chlorocadmate(II) assembly: Pivotal role of hydrogen bonding and H—H interactions

Experimental and theoretical insights into the formation of weak hydrogen bonds and H⋯H bonding interactions in the solid-state structure of two eucalyptol derivatives

“…These results are similar to those reported by Hajji and co-workers. 54 We have used one theoretical model to estimate the contribution from C-HÁ Á ÁO and C-HÁ Á ÁH-C bonding interactions in the solid-state dimer shown in Fig. 7a.…”

The Unconventional Noncovalent Interactions Control: Crystallographic and Theoretical Analyses of the Crystalline Structure of 1,1′‐(1‐Chloro‐4‐methoxyphenyl)dibenzene as a Case Study

“…Moreover, CÀ H…HÀ C contacts which represent a unique type of CÀ H … X hydrogen bonding, have engendered a stimulating debate among researchers, [17][18][19][20] with supporting evidence for their stabilizing contribution. [21][22][23][24] These dispersion-dominated interactions exhibit hydrogen bonding-like characteristics and have notable application in various fields, including synthetic chemistry, [25] crystal engineering, [26,27] and hydrogen storage materials [28] etc. Furthermore, unconventional halogen-halogen (X⋯X) interactions have been the subject of considerable interest for many years.…”

“…In reference, [16] as instance, the importance of the C−H⋅⋅⋅O hydrogen bond is also demonstrated in achieving the Rh 2 (II)‐catalyzed asymmetric cycloisomerization of 1,n‐enynes by synergistically activating the substrate and introducing the C−H…O bonds. Moreover, C−H…H−C contacts which represent a unique type of C−H … X hydrogen bonding, have engendered a stimulating debate among researchers, [17–20] with supporting evidence for their stabilizing contribution [21–24] . These dispersion‐dominated interactions exhibit hydrogen bonding‐like characteristics and have notable application in various fields, including synthetic chemistry, [25] crystal engineering, [26,27] and hydrogen storage materials [28] etc.…”

Insight into non-covalent interactions in a tetrachlorocadmate salt with promising NLO properties: Experimental and computational analysis

“…Organo-metal halides assembly investigation represents for a quite while one of the most active areas of chemical research and material science due to their designable and tuneable characteristics as well as their potential applications in numerous fields including In particular, Halogenocadmates(II) crystal chemistry is exceptionally diverse due to the fact that Cd 2+ is a d 10 metal ion. It demonstrated a propensity for forming a variety of crystalline structures by self-assembling from suitable solution mixtures, their structural flexibility enables a great variety of structural archetypes to be constructed in the form of onedimensional linear chains [5], two-dimensional layers [6], and ribbon-like structures [7].…”