Abstract:Amorphous carbon films have several outstanding tribology characteristics, including high hardness, surface smoothness, and low friction. Under tribological conditions, their surface is generally exposed to high-temperature and pressure. Although the structure of amorphous carbon films is likely changed by high temperature and pressure, there have been no reports on such structural changes of the films. To obtain information about their structural changes, synchrotron X-ray diffraction was used to analyze two … Show more
“…The appropriate material composition of a-C films plays a crucial role in determining their comprehensive performances. When used as a tribo-couple material, a-C films offer excellent anti-friction and -wear, leading to improved performances and the extended lifespan of a-C films [102,103]. Additionally, their good adhesion to substrates contributes to reduced friction and wear.…”
Section: Materials Composition Of Tribo-couplesmentioning
Diamond-like carbon (DLC) film has gained widespread popularity as a versatile and important solid lubricant material in the field of tribology. Among various types of DLC films, hydrogen-rich DLC (a-C:H) film as a high-performance material has greatly enhanced anti-friction and anti-wear. However, despite its remarkable capabilities, the surface chemical properties and tribological performance of a-C:H film are significantly influenced by the surrounding environment, in special atmospheric conditions. Its super-slip mechanism involves the participation of hydrogen atoms, which can weaken the normal electron number of the outermost layer of a-C:H film. What is more, it is essential to investigate tribofilms in a vacuum or inert gas environment to ascertain the appropriate tribological properties of a-C:H film, which helps in mitigating oxidation effects. When non-doped DLC films are subjected to friction in a dry nitrogen or argon environment, they create sp3-C-rich transfer films on the contact surface, resulting in macroscopic super-slip effects. This paper aims to introduce and discuss the diverse nanostructures of in situ tribofilms in a-C:H film, focusing on the working environment, and explore the prospective application directions of a-C:H film.
“…The appropriate material composition of a-C films plays a crucial role in determining their comprehensive performances. When used as a tribo-couple material, a-C films offer excellent anti-friction and -wear, leading to improved performances and the extended lifespan of a-C films [102,103]. Additionally, their good adhesion to substrates contributes to reduced friction and wear.…”
Section: Materials Composition Of Tribo-couplesmentioning
Diamond-like carbon (DLC) film has gained widespread popularity as a versatile and important solid lubricant material in the field of tribology. Among various types of DLC films, hydrogen-rich DLC (a-C:H) film as a high-performance material has greatly enhanced anti-friction and anti-wear. However, despite its remarkable capabilities, the surface chemical properties and tribological performance of a-C:H film are significantly influenced by the surrounding environment, in special atmospheric conditions. Its super-slip mechanism involves the participation of hydrogen atoms, which can weaken the normal electron number of the outermost layer of a-C:H film. What is more, it is essential to investigate tribofilms in a vacuum or inert gas environment to ascertain the appropriate tribological properties of a-C:H film, which helps in mitigating oxidation effects. When non-doped DLC films are subjected to friction in a dry nitrogen or argon environment, they create sp3-C-rich transfer films on the contact surface, resulting in macroscopic super-slip effects. This paper aims to introduce and discuss the diverse nanostructures of in situ tribofilms in a-C:H film, focusing on the working environment, and explore the prospective application directions of a-C:H film.
“…For some application, diamond like carbon coatings need to withstand both high temperature (HT) and high pressure (HP). The limited work has been conducted to investigate the stability of DLC coatings under both thermal and pressure conditions [2]. Some interesting synergetic effect of temperature and pressure on the stability of DLC films was revealed [3].…”
The aim of this paper was to systemically study the pressure influence of the bonding of four types of DLC coatings during annealing in high temperatures (HT) and high pressures (HP). The results show that in the two silicon free coatings, Cr2C3 crystal are found to be generated during the argon annealing, but no obvious phase transformation was observed in the two silicon containing coatings when annealed at the same temperature, the sp3 content of HIPped samples is to some extent higher than that of argon annealed samples. The influence of high pressure is more significant on the hydrogenated DLC than on the hydrogen free DLC. Si dopant can inhibit the formation of chromium carbides during the argon and HIP annealing treatment. The hydrogen-free DLC coatings are more stable than the hydrogenated DLC coatings; silicon containing DLC coatings possess a better stability than silicon free DLC coatings. The high pressure can delay the carbon bonding change from sp3 to sp2 or graphitisation. Based on sp3 content, DCr coating (hydrogenated and silicon free coating) was the most unstable coating under both high temperature and high pressure condition, while GCrSi coating (hydrogen-free and silicon containing coating) was the most stable coating.
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