Strong Uptake of Gas-Phase Organic Peroxy Radicals (ROO•) by Solid Surfaces Driven by Redox Reactions
Olivier Durif,
Felix Piel,
Armin Wisthaler
et al.
Abstract:Organic peroxy radicals (ROO • ) are key oxidants in a wide range of chemical systems such as living organisms, chemical synthesis and polymerization systems, combustion systems, the natural environment, and the Earth's atmosphere. Although surfaces are ubiquitous in all of these systems, the interactions of organic peroxy radicals with these surfaces have not been studied until today because of a lack of adequate detection techniques. In this work, the uptake and reaction of gas-phase organic peroxy radicals … Show more
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