“…There are several ways to introduce dopants [15]. These are (1) hole doping is achieved with substituting A for monovalent B + (B ¼ Cs, K, Na) atoms partially in the blocking layer, and this substitution should add an excess hole into the system, for example, Ba 1−x K x Fe 2 As 2 [16,17] (2) partially substitute Fe for transition metals (Co, Ni, Pd, Rh) into FeAs layers and yields electrons into the system. In this method, dopants are directly doped into the Fe layer, which can stabilize the system; for example, Co (A(Fe 1−x Co x ) 2 As 2 ), Rh (A(Fe 2−x Rh x ) As 2 ), Ni (A(Fe 1−x Ni x ) 2 As 2 ) [18][19][20] and we get electrondoped pnictides that form an abundant phase diagram where superconductivity and magnetism exist together, and (3) replacing arsenic partially with phosphorus, and phosphorus generates a chemical pressure effect that suppress SDW and emerges superconductivity at the corresponding unit cell volume [21,22].…”