We study spin relaxation and diffusion in an electron-spin ensemble of nitrogen impurities in diamond at low temperature (0.25-1.2 K) and polarizing magnetic field (80-300 mT). Measurements exploit mode-and temperature-dependent coupling of hyperfine-split sub-ensembles to the resonator. Temperature-independent spin linewidth and relaxation time suggest that spin diffusion limits spin relaxation. Depolarization of one sub-ensemble by resonant pumping of another indicates fast cross-relaxation compared to spin diffusion, with implications on use of sub-ensembles as independent quantum memories.PACS numbers: 42.50.Pq, 03.67.Lx The study of spin ensembles coupled to superconducting integrated circuits is of both technological and fundamental interest. An eventual quantum computer may involve a hybrid architecture [1-4] combining superconducting qubits for processing of information, solid-state spins for storage, and superconducting resonators for interconversion. Additionally, superconducting resonators allow the study of spin ensembles at low temperatures with ultra-low excitation powers and high spectral resolution [5,6]. While one spin couples to one microwave photon with strength g/2π ∼ 10 Hz, an ensemble of N spins collectively couples with g ens = g √ N [7,8], reaching the strong-coupling regime g ens > κ, γ at N 10 12 [8][9][10], where κ and γ are the circuit damping and spin dephasing rates, respectively.Among the solid-state spin ensembles under consideration, nitrogen defects in diamond (P1 centers) [11] are excellent candidates for quantum information processing. Diamond samples can be synthesized with P1 centers as only paramagnetic impurities. Additionally, samples with spin densities ranging from highly dense (> 200 ppm) to very dilute (< 5 ppb) are commercially available, allowing the tailoring of spin linewidth (γ ∝ N [12]) and collective strength (g ens ∝ √ N ). In contrast to nitrogen-vacancy centers in diamond [13] and rare-earth ions in Y 2 SiO 5 [14, 15], P1 centers are optically inactive, making a coupled microwave resonator an ideal probe for their study. However, the magnetic fields 100 mT needed to polarize the ensemble at the few-GHz transition frequencies of circuits [16] must not compromise superconductivity. The freezing of all spin dynamics in a high-purity P1 ensemble by the field would allow quenching spin decoherence [17] through dynamical decoupling [18], realizing a useful quantum memory. * These authors contributed equally to this work.Here, we investigate the dynamics of a P1 electron-spin ensemble probed by controlled coupling to two modes of a coplanar waveguide (CPW) resonator. The resonator is patterned on a NbTiN film [19] withstanding applied magnetic fields beyond 300 mT. Three hyperfine-split spin sub-ensembles are clearly resolved over the temperature range 0.25-1.2 K. The collective coupling of each arXiv:1208.5473v1 [cond-mat.mes-hall]