Strong Exciton-Vibrational Coupling in Molecular Assemblies. Dynamics using the Polaron Transformation in HEOM Space
Joachim Seibt,
Oliver Kühn
Abstract:In the context of Frenkel exciton dynamics in aggregated molecules the polaron transformation technique facilitates a treatment where diagonal elements attributed to electronic excited-state populations are decoupled from fluctuations associated with vibrational degrees-of-freedom. In this article we describe for the first time how the polaron transformation can be applied in the context of the "Hierarchical Equations of Motion" (HEOM) technique for treatment of open quantum systems with all vibrational compon… Show more
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