Strong Down-Conversion Emission of Sm³⁺ Doped Borotellurite Glass under 480 nm Excitation Wavelength

Abstract

Tellurite glasses were generally applied in rare earth optical materials due to their excellent in physical and chemical properties. In this study, tellurite glasses composed of (70-x)TeO2-20B2O3-10ZnO-xSm2O3 (x = 0.0, 0.5, 1.0, 1.5, 2.0 and 2.5 mol %) were prepared by conventional melt-quenching technique. Some basic physical parameters such as density, molar volume and oxygen packing density as well as the optical analysis by mean of their absorption and emission spectra have been carried out at room temperature using UV/Vis and photoluminescence spectrophotometer. The result of physical properties are found to vary with respect to concentration of Sm3+ ions content. Meanwhile, three strong absorption peaks are observed and are well resolved in the ultra violet and visible regions due to transitions between the ground state and various excited state of Sm3+ ions. Under 480nm laser excitation, luminescence spectra exhibit four emission bands at 562 nm, 599 nm, 645 nm and 706 nm which corresponding to the transition 4G5/2 → 6H5/2, 4G5/2 → 6H7/2, 4G5/2 → 6H9/2 and 4G5/2 → 6H11/2 were observed. Some other results were also been analysed and presented.