Controlling decoherence is the biggest challenge in efforts to develop quantum information hardware [1][2][3] . Single electron spins in gallium arsenide are a leading candidate among implementations of solid-state quantum bits, but their strong coupling to nuclear spins produces high decoherence rates [4][5][6] . Group IV semiconductors, on the other hand, have relatively low nuclear spin densities, making them an attractive platform for spin quantum bits. However, device fabrication remains a challenge, particularly with respect to the control of materials and interfaces 7 . Here, we demonstrate state preparation, pulsed gate control and charge-sensing spin readout of hole spins confined in a Ge-Si core-shell nanowire. With fast gating, we measure T 1 spin relaxation times of up to 0.6 ms in coupled quantum dots at zero magnetic field. Relaxation time increases as the magnetic field is reduced, which is consistent with a spin-orbit mechanism that is usually masked by hyperfine contributions.Since the proposal of Loss and DiVincenzo's 1 , the promise of quantum dots for solid-state quantum computation has been underscored by the successful initialization, manipulation and readout of electron spins in GaAs systems 5,[8][9][10] . The electronic wavefunctions in these systems typically overlap with a large number of nuclear spins that are difficult to control and in most cases thermally randomized. The resulting intrinsic spin decoherence rates 4-6 have been successfully reduced by spin-echo techniques 6,11 , but require complex gate sequences that complicate multi-qubit operations 12 . The prospect of achieving long coherence times in group IV materials with few nuclear spins has stimulated many proposals 13,14 and intensive experimental efforts [15][16][17][18][19] , and crucially depends on the development of high-quality host materials. Recent advances regarding single quantum dots have been achieved using Zeeman splitting for readout with a finite magnetic field [19][20][21][22][23] . Coupled quantum-dot devices 13,[15][16][17][18]24 in a nuclear spin-free system are more desirable for flexible quantum manipulation 25 but more challenging, and characterization of the spin lifetime has yet to be completed.Semiconductor nanowires form a favourable platform for quantum devices because of the ability to precisely control their diameter, composition, morphology and electronic properties during synthesis 26 . The prototypical Ge-Si nanowire heterostructure has revealed diverse phenomena at the nanoscale and enabled numerous applications in nanoelectronics. The epitaxial growth of silicon around a single-crystal germanium core (Fig. 1, inset) and the associated valence band offset provide a natural radial confinement of holes that, due to the large sub-band spacing, behave onedimensionally at low temperature 27 . Although the topmost valence band has been predicted to be twofold degenerate and of lighthole character under idealized approximations 28 , it is generally expected that mixing between heavy and light hole...