Evaluation of thermal destruction of refractories has been a subject of numerous studies [1][2][3][4]. However, there are very few investigations giving comparative data on the thermal destruction process of fired [5][6][7][8][9] and unfired [5,9] refractory materials and in the case of unfired high-refractory concretes, such data are not available.During service, refractory materials are usually subjected to the action of variable thermal loads. If the destruction of the refractories starts prior to the attainment of the stationary themal condition (steady-state), the process of crack growth consumes not only the potential energy of deformation that is associated with the heterogeneity of the material, but also the energy of thermoelastic stresses developed due to the presence of a temperature gradient within the body being heated.However, until the present time, comparative studies of thermal shock resistance have been carried out with respect to the experimentally determined thermal, physical, and mechanical characteristics of the materials subjected to thermal loads. The concepts of fracture mechanics are also used [2] for determining the ability of the material to resist the growth of thermal cracks.A significant shortcoming of these criteria of thermal shock resistance is that they refer to the linear-elastic materials whose brittleness index X is equal to unity.In practice, thermal shock resistance is determined in the thermal shock regime according to GOST 7875-83, i.e., by maintaining the conditions under which destruction of a refractory specimen occurs mainly due to the elastic energy accumulated in it as a result of rapid thermal deformation during the period of fast cooling (quenching). In reality, such conditions are rarely encountered.During service, unfired refractory concretes experience differential heating across the thickness and the maximum temperature leads to the formation (forming) of the working layer of the lining with insignificant structural changes in the nonworking (inoperative) region. Consequently, the working portion of the lining is subjected to thermal shock during the process of heating and evolution of a strong structure.We carried out studies on the criterional evaluation of the thermal destruction of the corundum concretes exhibiting constancy of volume [i0] using the previously described apparatus and according to the developed procedures [11][12][13][14] taking into account the specific features of deformation of these materials during loading.In the case of nonlinearly deforming materials (0 < X < I), we used the experimentally measured strains for evaluating (calculating) the criteria of thermal shock resistance that characterize the resistance of the material to crack nucleation; the magnitude of the elastic energy accumulated up to the beginning of the destruction of the material was used for evaluating the criteria characterizing the fracture resistance. The effect of the structural features of the concretes on their resistance to thermal destruction was studied on th...