Strategies for the preparation of high-performance inorganic mixed-halide perovskite solar cells

Liu, Xin; Li, Jie; Cui, Xumei; Wang, Xiao; Yang, Dingyu

doi:10.1039/d2ra05535j

Cited by 17 publications

(7 citation statements)

References 151 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…In recent years, lead halide perovskite materials with the structure ABX 3 (where A is caesium, B is a lead cation and X is a halide anion) exhibit numerous advantages such as high brightness, and high photoluminescence quantum yield (PLQY) with narrow size distribution, which can provide great potential in optoelectronic devices [1]. These lead halide perovskite-based various applications such as solar cells [2][3][4][5][6][7][8][9], photodetectors [10], light-emitting diodes (LEDs) [11][12][13][14][15][16][17] and low-threshold lasers [18][19][20], etc., have been increasingly investigated. Although they have excellent optical properties, the lead halide perovskite materials' sensitive surface chemistry with moisture, oxygen in the ambient environment, and organic polar solvents are still one of the major issues.…”

Section: Introductionmentioning

confidence: 99%

SiO ₂ -coated lead halide perovskites core–shell and their applications: a mini-review

Trinh,

Ahmad

2024

R. Soc. Open Sci.

View full text Add to dashboard Cite

Research on lead halide perovskites has demonstrated that they are one of the potential materials for optoelectronic and bio-related applications owing to their promising optical and electronic properties. However, their poor chemical stability in ambient environments is a critical factor that affects their practical applications. Silica is known for its excellent environmental/chemical stability and good optical properties. Therefore, SiO 2 -coated lead halide perovskites have been studied by introducing the protective layer containing SiO 2 to prevent the rapid destruction of their surface chemistry and environmental degradation. It is found that lead halide perovskite core–shell can significantly improve the stability and preserve their high photoluminescence quantum yield. In addition, controlling the shell thickness is also important to produce effective and suitable inorganic halide perovskites core–shell for practical applications. This mini-review discusses the stability, synthesis method and applications of SiO 2 -coated lead halide perovskite core–shell. Furthermore, the effect of the SiO 2 shell thickness on lead halide perovskite core–shell-based applications is also reviewed.

show abstract

Section: Introductionmentioning

confidence: 99%

SiO ₂ -coated lead halide perovskites core–shell and their applications: a mini-review

Trinh,

Ahmad

2024

R. Soc. Open Sci.

View full text Add to dashboard Cite

show abstract

“…All-inorganic cesium lead halide (CsPbX 3 , X = I, Br) perovskites have attracted much attention because of their superior thermal stability over their organic–inorganic hybrid counterparts, according to both experimental and theoretical results. − Among the CsPbX 3 perovskite materials, the mixed halide CsPbI 2 Br is considered the most promising light absorber due to the trade-off between stability and efficiency. CsPbI 2 Br has excellent thermal/light soaking stability and a suitable band gap of ≈1.90 eV, which exhibits promising application potential in the front cell of tandem solar cells. , In recent years, the performance of CsPbI 2 Br perovskite solar cells (PSCs) has been rapidly improved through some innovations, such as modulating the crystallization process, optimizing composition, , and modifying the interface. , Yang et al reported a low-dimensional intermediate-assisted growth (LDIAG) method to control both nucleation and growth kinetics by introducing imidazole halide (IMX: IMI and IMBr) into the precursor solution .…”

Section: Introductionmentioning

confidence: 99%

Enhanced Efficiency and Stability of Inverted CsPbI₂Br Perovskite Solar Cells via Fluorinated Organic Ammonium Salt Surface Passivation

Cao,

Wang,

She

et al. 2024

Langmuir

Self Cite

View full text Add to dashboard Cite

All-inorganic perovskite solar cells (PSCs) have recently received increasing attention due to their outstanding thermal stability. However, the performance of these devices, especially for the devices with a p−i−n structure, is still inferior to that of the typical organic− inorganic counterparts. In this study, we introduce phenylammonium iodides with different side groups on the surface of the CsPbI 2 Br perovskite film and investigate their passivation effects. Our studies indicate that the 4-trifluoromethyl phenylammonium iodide (CFPA) molecule with the −CF 3 side group effectively decreases the trap density of the perovskite film by forming interactions with the undercoordinated Pb 2+ ions and significantly inhibits the nonradiative recombination in the derived PSC, leading to an enhanced open-circuit voltage (V oc ) from 0.96 to 1.10 V after passivation. Also, the CFPA post-treatment enables better energy-level alignment between the conduction band minimum of CsPbI 2 Br perovskite and [6,6]-phenyl C61 butyric acid methyl ester, thereby enhancing the charge extraction from the perovskite to the charge transport layer. These combined benefits result in a significant enhancement of the power conversion efficiency from 11.22 to 14.37% for inverted CsPbI 2 Br PSCs. The device without encapsulation exhibits a degradation of only ≈4% after 1992 h in a N 2 glovebox.

show abstract

“…The superior stability of all-inorganic CsPbX 3 perovskite materials compared to organic-inorganic hybrid halide perovskites is attributed to the sensitivity of organic molecules (such as MA + ) to light, heat, moisture, and irradiation, which decompose or damage the structure, limiting its application in storage, fabrication, and equipment manipulation processes [43][44][45]. The choice of synthesis technique likewise has an impact on the stability of the material.…”

Section: Introductionmentioning

confidence: 99%

Synthesis of All-Inorganic Halide Perovskite Nanocrystals for Potential Photoelectric Catalysis Applications

Wang

Liu

et al. 2023

Catalysts

View full text Add to dashboard Cite

Compared with conventional semiconductors, halide perovskite nanocrystals (NCs) have a unique crystal structure and outstanding optoelectronic properties, offering wide potential for applications in optoelectronic devices such as solar cells, photodetectors, light-emitting diodes, lasers, and displays. Rational technological design is providing vital support for the development of perovskite optoelectronics. Herein, monodisperse all-inorganic halide perovskite nanocrystals with consistent morphology and cubic crystal phase were synthesized employing a modified one-pot hot injection method to independently modulate the stoichiometric ratios of three precursors involving cesium salt, lead source, and halide. In combination with an anion exchange reaction, mixing two kinds of perovskite NCs with different halogens enables a transition from violet emission to green and finally to red emission over the entire visible region. Additionally, optical and electrochemical tests suggested that the as-synthesized halide perovskite NCs are promising for photoelectric catalysis applications.

show abstract

Strategies for the preparation of high-performance inorganic mixed-halide perovskite solar cells

Abstract: This review gives a full-scale and in-depth summary of mixed halide CsPbX3 perovskite materials for the photovoltaic application.

Cited by 17 publications

References 151 publications

SiO ₂ -coated lead halide perovskites core–shell and their applications: a mini-review

SiO ₂ -coated lead halide perovskites core–shell and their applications: a mini-review

Enhanced Efficiency and Stability of Inverted CsPbI₂Br Perovskite Solar Cells via Fluorinated Organic Ammonium Salt Surface Passivation

Synthesis of All-Inorganic Halide Perovskite Nanocrystals for Potential Photoelectric Catalysis Applications

Contact Info

Product

Resources

About

Strategies for the preparation of high-performance inorganic mixed-halide perovskite solar cells

Abstract: This review gives a full-scale and in-depth summary of mixed halide CsPbX3 perovskite materials for the photovoltaic application.

Cited by 17 publications

References 151 publications

SiO 2 -coated lead halide perovskites core–shell and their applications: a mini-review

SiO 2 -coated lead halide perovskites core–shell and their applications: a mini-review

Enhanced Efficiency and Stability of Inverted CsPbI2Br Perovskite Solar Cells via Fluorinated Organic Ammonium Salt Surface Passivation

Synthesis of All-Inorganic Halide Perovskite Nanocrystals for Potential Photoelectric Catalysis Applications

Contact Info

Product

Resources

About

SiO ₂ -coated lead halide perovskites core–shell and their applications: a mini-review

SiO ₂ -coated lead halide perovskites core–shell and their applications: a mini-review

Enhanced Efficiency and Stability of Inverted CsPbI₂Br Perovskite Solar Cells via Fluorinated Organic Ammonium Salt Surface Passivation