Strategies for the Construction of Supramolecular Compounds through Coordination Chemistry

Holliday, Bradley J.; Mirkin, Chad A.

doi:10.1002/1521-3773(20010601)40:11<2022::aid-anie2022>3.0.co;2-d

Cited by 1,536 publications

(170 citation statements)

References 386 publications

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“…These weak intermolecular interactions, especially, hydrogen bonds play a very important role in constructing metal-organic frameworks (MOFs) [20,21]. A wide range of one-or multi-dimensional infinite solid-state coordination architectures have been achieved in the last decade [15,17,[22][23][24][25][26][27][28][29][30][31][32], especially aromatic multibenzenecarboxylate ligands together with neutral N-based ligand, 4,4 0 -bipy, have been extensively employed in the construction of mixed-ligand MOFs [33][34][35].…”

Section: Introductionmentioning

confidence: 99%

Three isostructural 3D supramolecules with p-thioacetatebenzoic acid ligand: syntheses, structure characterizations, and properties

et al. 2010

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p-Thioacetatebenzoic acid (H 2 L) and a combination of N-donor ligand of 4,4 0 -bipyridine (4,4 0 -bipy) with metal(II) ions give rise to three 3D supramolecules of general formula [M(HL) 2 (4,4 0 -bipy) 2 (H 2 O) 2 ] Á H 2 O, M = Co II (1), Zn II (2), Ni II (3), which were characterized by crystallographic methods. The crystals are isostructural and belong to the triclinic P " 1 space group. The structure can be considered to construct from 1D chains and further linked by hydrogen bonds into the final 3D supramolecular networks. The electrochemical behavior of complexes 1 and 3 were studied by cyclic voltammetry, indicating that the electron transfers in the electrode reaction are irreversible. Meanwhile, complex 2 exhibits significantly red-shifted emission in solid state at room temperature.

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Section: Introductionmentioning

confidence: 99%

Three isostructural 3D supramolecules with p-thioacetatebenzoic acid ligand: syntheses, structure characterizations, and properties

et al. 2010

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“…Discrete or extended metallo-supramolecular modules made by metal-ion-directed self-assembly are of particular interest for the construction of technological devices [13]. They provide a set of well-defined coordination geometries, a range of binding strengths and ligand exchange kinetics that allow the reversible assembly-disassembly of supramolecular architectures that include switchable interaction sites.…”

Section: Introductionmentioning

confidence: 99%

Metallo-supramolecular modules as a paradigm for materials science

Kurth

2008

Science and Technology of Advanced Materials

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Metal ion coordination in discrete or extended metallo-supramolecular assemblies offers ample opportunity to fabricate and study devices and materials that are equally important for fundamental research and new technologies. Metal ions embedded in a specific ligand field offer diverse thermodynamic, kinetic, chemical, physical and structural properties that make these systems promising candidates for active components in functional materials. A key challenge is to improve and develop methodologies for placing these active modules in suitable device architectures, such as thin films or mesophases. This review highlights recent developments in extended, polymeric metallo-supramolecular systems and discrete polyoxometalates with an emphasis on materials science.

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“…During the past few decades, a number of supramolecular architectures that have versatile functions have been successfully designed and synthesized through self-assembly from different components via noncovalent interactions (such as hydrogen bonding and aromatic p-p stacking interactions), multiple intermolecular interaction [1][2][3][4][5][6][7][8][9][10]. Among the noncovalent interactions, hydrogen bonding and p-p stacking interactions are one of the most useful and flexible motifs to arrange molecular building blocks for the crystal engineering design of extended supramolecular structures [12][13][14][15][16][17][18][19][20][21][22]. They have the strong directionality to organize individual molecules into supramolecular aggregates that have precise topological structures [23][24][25].…”

Section: Introductionmentioning

confidence: 99%

A novel porous supramolecular complex constructed by the co-crystallization of melamine and sulfate via hydrogen bonds and aromatic π-π interaction

Yang

Xiang

et al. 2007

Struct Chem

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Co-crystallization of melamine(MA) and sulfate results in crystalline product [(C 3 H 7 The novel supramolecular complex has been characterized by elemental analysis, thermal analysis (TGA and DSC), nuclear magnetic resonance (NMR), and single crystal X-ray diffraction. X-ray crystallographic studies of the complex reveal that the title complex has a 3-D microporous structure which is linked by intense intermolecular hydrogen-bonding interactions (N-HÁÁÁÁÁÁO, N-HÁÁÁÁÁÁN, O-HÁÁÁÁÁÁO) and aromatic p-p interaction, which stabilize the whole crystal framework. The TGA curve shows that the complex is stable up to 500°C, above which its structure begins to collapse.

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Strategies for the Construction of Supramolecular Compounds through Coordination Chemistry

Cited by 1,536 publications

References 386 publications

Three isostructural 3D supramolecules with p-thioacetatebenzoic acid ligand: syntheses, structure characterizations, and properties

Three isostructural 3D supramolecules with p-thioacetatebenzoic acid ligand: syntheses, structure characterizations, and properties

Metallo-supramolecular modules as a paradigm for materials science

A novel porous supramolecular complex constructed by the co-crystallization of melamine and sulfate via hydrogen bonds and aromatic π-π interaction

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