Strategic Insertion of Heavy Atom to Tailor TADF OLED Material for the Development of Type I Photosensitizing Catalytic Red Emissive Assemblies
Manpreet Singh,
Manoj Kumar,
Vandana Bhalla
Abstract:The work presented in the manuscript describes a simple strategy for transforming thermally activated delayed fluorescent organic light‐emitting diodes (TADF OLEDs) compound 10‐(dibenzo[a,c]phenazin‐11‐yl)‐10H‐phenoxazine (DPZ‐PXZ) into type I photosensitizer 10‐(dibenzo[a,c]phenazin‐11‐yl)‐10H‐phenothiazine (DPZ‐PHZ) by strategically introducing sulfur atom in the photosensitizing core. The synthesized compound DPZ‐PHZ exhibits aggregation‐induced enhancement (AIE) and through‐space charge transfer (TSCT) … Show more
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