Straightforward Synthesis of Poly(dimethylsiloxane) Phases with Immobilized (1R)‐3‐(Perfluoroalkanoyl)camphorate Metal Complexes and Their Application in Enantioselective Complexation Gas Chromatography (Eur. J. Org. Chem. 21/2012)
Abstract:The cover picture shows the leaves and blossom of the camphor tree cinnamomum camphora (photo taken at the botanical garden of the Ruprecht Karls University Heidelberg), a natural source of (+)‐(1R)‐camphor, which is the chiral key moiety of immobilized (1R)‐3‐(perfluoroalkanoyl)camphorate metal complexes. The beautiful white blossom forms a structure with tetrahedral elements, which are “mirrored” in the model of the polymeric chiral stationary phase. This chiral stationary phase is accessible in large quanti… Show more
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