Stimuli‐responsive hydrogel microgels on porous silicon one‐dimensional photonic crystals: Tapping the full potential for optical sensor applications

Abstract

Porous silicon 1D photonic crystals, namely rugate filters, are covered with a loosely packed hexagonally ordered array of stimuli‐responsive hydrogel microgels, and the optical properties of the resulting hybrid sensor are thoroughly investigated. For this purpose, both rugate filters with and without hydrogel microgel on top are immersed in ethanol/water mixtures possessing different compositions and NaCl solutions. Reflectance spectra of all samples are taken and analyzed concerning the spectral positions and reflectance intensity of the strong peak related to the photonic crystal rugate peak as well as the side bands resulting from Fabry–Pérot interference at the interfaces bordering the porous silicon. For the latter analysis, a Fourier transform is applied to the side bands for calculating the effective optical thickness (EOT). Thereby it can be shown that the spectral position of both the rugate peak and the EOT peak is best suited for monitoring refractive index changes in the immersion medium whereas the swelling and collapse of the stimuli‐responsive hydrogel microgel can be only detected by variations in the amplitude of the rugate peak and the EOT peak. These results are confirmed by simulations using a simple geometrical model and shall serve as guide for developing tailor‐made optical sensors.

Special Issue on Advances in Porous Materials

“…Next, Pacholski and colleagues fabricated a hybrid sensor made of photonic rugate filters obtained by wet electrochemical etching of silicon and covered them with a stimuli-responsive hydrogel microgels [27]. The authors then demonstrated the potential for developing optical sensors that can detect simultaneously and independently two parameters-the refractive index of the immersion medium and the swelling or collapse of hydrogel microgels.…”