Stimulation of High Temperature SAGD Producer Wells Using a Novel Chelating Agent (GLDA) and Subsequent Geochemical Modeling Using PHREEQC

Abstract

Acidizing of sour, heavy oil, weakly consolidated sandstone formations under steam injection is a real challenge. Fines migration, sand production, inorganic scale, corrosion products, and damage due to asphaltene precipitation are some of the common concerns with these sandstone formations. They cause decline in the productivity of the wells, and there is always need to stimulate these wells to restore their productivity. Furthermore, the complexities of sandstone formations require a mixture of acids and several additives, especially at temperatures up to 360°F. Three treatments were tried in a horizontal well in this field: HCl acid, A (GLDA), and B chelating agents. In this paper, we evaluate the results of field applications using geochemical modelling, production data, and analysis of well flow back fluids after field treatments.The field treatment included pumping a foaming agent to have proper rheological characteristics and a better controlled pumping process, followed by the main stage of the treatments. The treatment fluids were displaced into the formation by pumping produced water and were allowed to soak for 6 hours, then the well was put on production, and samples of flowback fluids were collected. The concentrations of key cations were determined using ICP, and the chelate concentration of the chelating agent A was measured utilizing a titration method using ferric chloride solution. Geochemical modelling was conducted using specialized software, and was used to predict the concentrations of key ions in the flow back samples.The first two treatments including HCl acid and chelating agent B produced results below expectation. The third treatment using GLDA was successful and the well productivity increased significantly. The treatment was applied in the field without encountering any operational problems. A significant gain in oil production was achieved without adversely impacting the water cut, causing sand production, or fines migration. Analysis of flow back samples indicated that iron was the main cation, which shows that the chelate dissolved corrosion products. Geochemical modelling was able to predict the trend noted in the concentrations of key ions and chelant in the produced fluids.

From initial treatment design to final disposal of chelating agents: a review of corrosion and degradation mechanisms

“… 71 GLDA has also been used to successfully stimulate SAGD producing wells. 154 HEIDA has also been shown to be an effective scale remover that can be used in place of EDTA. 14 Sopngwi et al 155 used an APCA/HF (hydrofluoric acid) system to successfully stimulate a well in a sandstone reservoir in the Gulf of Mexico and showed an increase in the production rate of 30%, while the acid system showed a corrosion rate of 14.5 mmpy (0.016 lb ft −2 ) on 13Cr in the presence of 0.6% inhibitor.…”

Reaction Kinetics and Coreflooding Study of High-Temperature Carbonate Reservoir Stimulation Using GLDA in Seawater

“…HCl based matrix acidizing formulations are usually loaded with additives, such as corrosion inhibitors, water-wetting surfactants, iron control agent, anti-sludge agents, iron control agents, etc. GLDA acid treatment does not require any additives since GLDA itself acts as iron control agent, has low interfacial tension (IFT), acts as surfactant, and does not cause asphaltene precipitation [35]. Using GLDA will eliminate the need for the numerous additives used in the case of HCl treatment.…”

Development of Chelating Agent-Based Polymeric Gel System for Hydraulic Fracturing

“…The results clearly indicate that the viscosity thickening effect can be controlled with the concentration of GLDA, and for optimum conditions, it should not be more than 30 wt %. All of the stimulation operations in the field are performed with a concentration of 20 wt % because it was found to be the optimum in case of stimulation [37][38][39]. In this case, 20% of GLDA also showed the optimum results.…”