“…23 Especially in catalysis, MOFs, as emerging porous non-homogeneous catalysts, show remarkable potential 24 in reactions such as oxidations, 25 reductions, 26 couplings 27 and cyclisations. 28 [Cu 3 (BTC) 2 (H 2 O) 3 ] n (Cu-BTC, HKUST-1), as a typical representative of MOFs, has been widely used in a variety of organic reactions, 29 including couplings, 30 cyclizations, 31 oxidizations 32 and boronation reactions. 33 However, the Cu-BTC-catalyzed construction of C–X bonds is still under investigation.…”