Stereoselective synthesis of substituted 1,3-dienes from propargylic esters: electrophilic-metal or redox catalysis?

Dai, Mengfu; Song, Liangliang; Chen, Liang-An

doi:10.1007/s11426-023-1925-4

Sci. China Chem.

2024

DOI: 10.1007/s11426-023-1925-4

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Stereoselective synthesis of substituted 1,3-dienes from propargylic esters: electrophilic-metal or redox catalysis?

Mengfu Dai,

Liangliang Song,

Liang-An Chen

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Transition Metal‐Catalyzed Synthesis of 1,2,3,4‐Tetrasubstituted 1,3‐Dienes from Propargylic Esters

Dai,

Kabandula,

Tai

et al. 2024

ChemCatChem

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Transition metal‐catalyzed synthesis of propargylic esters has been widely investigated, offering distinctive opportunities to build 1,3‐diene skeletons. Access to 1,2,3,4‐tetrasubstituted 1,3‐dienes has been a longstanding challenge in organic synthesis due to a great diversity of stereoisomers from four substituents and unpredictable regioselectivity. Given the synthetic challenges and the importance, inventing methods for the generation of this valuable architecture has gathered much more attention. Recently, several intriguing works concerning this topic have been achieved towards the high regio‐ and stereoselective elaborate 1,2,3,4‐tetrasubstituted 1,3‐dienes. Herein, this concept summarizes recent advances in transition metal‐catalyzed construction of 1,2,3,4‐tetrasubstituted 1,3‐dienes from propargylic esters, dividing into cyclic 1,3‐dienes, linear 1,3‐dienes (symmetrical and non‐symmetrical variants), and discussing the mechanism as well as their application.

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Transition Metal‐Catalyzed Synthesis of 1,2,3,4‐Tetrasubstituted 1,3‐Dienes from Propargylic Esters

Dai,

Kabandula,

Tai

et al. 2024

ChemCatChem

View full text Add to dashboard Cite

show abstract

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Stereoselective synthesis of substituted 1,3-dienes from propargylic esters: electrophilic-metal or redox catalysis?

Cited by 1 publication

References 145 publications

Transition Metal‐Catalyzed Synthesis of 1,2,3,4‐Tetrasubstituted 1,3‐Dienes from Propargylic Esters

Transition Metal‐Catalyzed Synthesis of 1,2,3,4‐Tetrasubstituted 1,3‐Dienes from Propargylic Esters

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