Stereoselective Synthesis and Conformational Analysis of Aromatic C‐Thionucleosides.

Juarez, Ernesto; García, Adrián Luis García; Hommer, Herbert; Salas, Magali; Gordillo, Barbara

doi:10.1002/chin.200638106

ChemInform

2006

DOI: 10.1002/chin.200638106

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Stereoselective Synthesis and Conformational Analysis of Aromatic C‐Thionucleosides.

Ernesto Juarez

Adrián Luis García García

Herbert Hommer

et al.

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2009

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“…For example, cinnamaldehyde was used as a starting material for the synthesis of various heterocyclic compounds, including tetrahydrothiophene [1], dihydropyridine [2], hexahydro-1H-pyrrolizine [3], benzo[a]quinolizidine [4], and pyrido[1,2-a]indole [5] derivatives.…”

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confidence: 99%

(2E)-3-(3-Methoxy-1-phenyl-1H-pyrazol-4-yl)-2-propenal

Kleizienė

Arbačiauskienė

Hölzer

et al. 2009

Molbank

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Abstract:The palladium-catalyzed reaction of 4-bromo-3-methoxy-1-phenyl-1H-pyrazole with acrolein diethyl acetal gives the title compound in good yield. In recent years efficient protocols for the preparation of aromatic 2,3-unsaturated aldehydes by Heck type palladium catalyzed cross-coupling reactions of arylhalides with acrolein diethylacetal [6][7][8] or 3,3-diacetoxypropene [9] have been developed. These methods allowed also to prepare (hetero)aromatic 2,3-unsaturated aldehydes containing pyridine, chinoline, isoquinoline, thiophene and benzothiophene nuclei [6][7][8][9].As a result of our interest in the synthesis of functionalized pyrazoles [10-13], we have developed a synthetic pathway to (2E)-3-(1-phenyl-3-methoxy-1H-pyrazol-4-yl)-2-propenal as a precursor to biologically active compounds and materials for non-linear optics. OPEN ACCESS

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mentioning

confidence: 99%

(2E)-3-(3-Methoxy-1-phenyl-1H-pyrazol-4-yl)-2-propenal

Kleizienė

Arbačiauskienė

Hölzer

et al. 2009

Molbank

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Stereoselective Synthesis and Conformational Analysis of Aromatic C‐Thionucleosides.

Cited by 1 publication

References 1 publication

(2E)-3-(3-Methoxy-1-phenyl-1H-pyrazol-4-yl)-2-propenal

(2E)-3-(3-Methoxy-1-phenyl-1H-pyrazol-4-yl)-2-propenal

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