Stereoselective Synthesis and Acaricidal Activity of Novel Thiazolidinones

Kasahara, I.; Matsui, N.; Yamada, Tuneo; Kaeriyama, Minoru; Ishimitsu, Keiichi

doi:10.1021/bk-1991-0443.ch027

Cited by 9 publications

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“…46 The reduction of an oxime to an amine has been also successfully applied in the synthesis of the herbicides thiencarbazonemethyl 47 and indaziflam, 48 the fungicides benzovindiflupyr 49 and pydiflumetofen 50 as well as the insecticides and acaricides etoxazole 51 and hexythiazox. 52…”

Section: Oximes As Intermediates In the Synthesis Of Agrochemicals No...mentioning

confidence: 99%

Oxime chemistry in crop protection

Lamberth

2024

Pest Management Science

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An overview is given on the significance of the oxime moiety in crop protection chemistry. This review focuses on the two most important aspects of agrochemical oximes, which are the occurrence and role of oxime groups in compounds with herbicidal, fungicidal and insecticidal activity, as well as the application of oxime derivatives as intermediates in the synthesis of crop protection agents not bearing any oxime function. Especially noteworthy is the fact, that in the synthesis of agrochemicals, oximes can be cyclized to isooxazoline, isoxazole, oxadiazole, oxazine, pyrrole, isothiazole and imidazole rings. © 2024 Society of Chemical Industry.

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Section: Oximes As Intermediates In the Synthesis Of Agrochemicals No...mentioning

confidence: 99%

Oxime chemistry in crop protection

Lamberth

2024

Pest Management Science

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“…2‐Thiazolidinones ( 87 ) were prepared by this type of synthesis starting from dithiocarbamates ( 85 ), which generates the intermediates ( 86 ) upon acidic treatment to give 87 (Scheme ), as shown by Kasahara et al …”

Section: Introductionmentioning

confidence: 99%

Short Review on the Synthesis of Thiophene, Pyrazole, and Thiazole Derivatives

Elkanzi

2017

J Chinese Chemical Soc

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The review summarizes the synthesis of different thiophene, pyrazole, and thiazole derivatives by refluxing 9a in ethanol with a catalytic amount of TEA or leaving it in DMF containing potassium carbonate at room temperature overnight to afford the corresponding thiophene derivative 10a. In addition, cyclization of Schiff bases with thioglycollic acid in the presence of a catalytic amount of ZnCl2 yielded novel thiophene derivatives. Condensation of 2‐substituted‐4‐methylythio semi‐carbazides 92 with carbonyl compounds under strong acidic conditions afforded 2‐thiazolines. Also, carboxylic acid reacted with 2‐thioethylamine in the presence of triphenylphosphine and triethylamine to afford 2‐thiazolines 98.

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Chitin Synthesis

2007

Modern Crop Protection Compounds

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Stereoselective Synthesis and Acaricidal Activity of Novel Thiazolidinones

Cited by 9 publications

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Oxime chemistry in crop protection

Oxime chemistry in crop protection

Short Review on the Synthesis of Thiophene, Pyrazole, and Thiazole Derivatives

Chitin Synthesis

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