“…Therefore, the synthetic access is challenging. [ 26 , 27 , 28 , 29 , 30 , 31 , 32 , 33 , 34 , 35 , 36 , 37 , 38 , 39 , 40 , 41 , 42 ] Although the documented synthetic strategies provide access to chiral silanols, many works focus on the synthetic aspect, while studies on the stability and subsequent chemistry of these components are still underrepresented. These are important for silanols, since the configuration of silanols in solution is not necessarily stable, as described for a bioactive silanol, documenting a racemization of the Si‐chiral compounds in aqueous medium.…”