2011
DOI: 10.1055/s-0031-1282213
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Stereoisomeric composition of two bioflavonoids from Larix sibirica

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Cited by 9 publications
(6 citation statements)
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“…At the same time, the peaks of C5-C10 in ring A of LC-oligoDHQ (Fig. 6b) Thus, the results of the comparative analysis of 1 Н and 13 C NMR spectra of DHQ monomer and LC-oligoDHQ, as well as some literature data on related compounds [22,[29][30][31] allow us to assume that LC-catalyzed oxidation of DHQ starts with the removal of hydrogen from the hydroxyl group at C3 to produce an active radical, which can be predominantly attached to C2 , C5 or C6 carbons of another molecule of monomer.…”
Section: Resultssupporting
confidence: 64%
See 1 more Smart Citation
“…At the same time, the peaks of C5-C10 in ring A of LC-oligoDHQ (Fig. 6b) Thus, the results of the comparative analysis of 1 Н and 13 C NMR spectra of DHQ monomer and LC-oligoDHQ, as well as some literature data on related compounds [22,[29][30][31] allow us to assume that LC-catalyzed oxidation of DHQ starts with the removal of hydrogen from the hydroxyl group at C3 to produce an active radical, which can be predominantly attached to C2 , C5 or C6 carbons of another molecule of monomer.…”
Section: Resultssupporting
confidence: 64%
“…It is a group of peaks assigned to quaternary carbons at 191-193 ppm. Analysis of literature data enables us to assume that these peaks ought to be assigned to C4 carbonyl group, and the high field shift may be attributed to the gammaeffect caused by the replacement of the hydroxyl in position 3 with an alkoxy group [22,[29][30][31].…”
Section: Resultsmentioning
confidence: 99%
“…Fomichev et al (2016) first drew attention to the potential of bioflavonoids obtained from bark of Siberian larch (Larix sibirica). Analysis of stereoisomeric composition demonstrated two bioflavonoids derived from Siberian larch (Larix sibirica) (Kolesnik et al 2011). As a result of its healthy effects Fomichev et al (2016) supposed that 1-5 g Larix sibirica dihydroquercetin powder (DHQ-1)/kg supplementation can be used for the realisation of a productive potential of lambs under an impact of stress-factors.…”
Section: Introductionmentioning
confidence: 99%
“…Fomichev et al (2016) first drew attention to the potential of bioflavonoids obtained from bark of Larix spp. Analysis of stereoisomeric composition demonstrated two bioflavonoids derived from Siberian larch (Larix sibirica) (Kolesnik et al, 2011). As a result of its healthy effects Fomichev et al (2016) supposed that 1-5 g Larix dahurica Turcz dihydroquercetin preparation DHQ1/kg supplementation can be used for the realisation of a productive potential of lambs under an impact of stress-factors.…”
Section: Introductionmentioning
confidence: 99%