Ad iastereoselective and stereodivergent rhodiumcatalyzedintramolecular coupling of sulfonylcarbamates with terminal allenes is described and it provides selective access to 1,3-aminoalcohol derivatives,s caffolds found in bioactive compounds.T he reaction is compatible with al arge range of different functional groups,thus furnishing products with high diastereoselectivities and yields.M oreover,m ultigram scale reactions,a sw ell as the application of suitable product transformations were demonstrated.