Stereocontrolled Synthesis of (.+‐.)‐Methyl 3,6‐Epoxy‐4,6,8‐triethyl‐2,4,9‐dodecatrienoate, a Major Metabolite of Caribbean Sponge, Plakortis halichondrioides, Using Reactions of Alkylidenecarbenes in One Pot.

Abstract

Other natural products U 0800Stereocontrolled Synthesis of (±)-Methyl 3,6-Epoxy-4,6,8-triethyl-2,4,9-dodecatrienoate, a Major Metabolite of Caribbean Sponge, Plakortis halichondrioides, Using Reactions of Alkylidenecarbenes in One Pot. -(AKIYAMA, M.; ISODA, Y.; NISHIMOTO, M.; KOBAYASHI, A.; TOGAWA, D.; HIRAO, N.; KUBOKI, A.; OHIRA*, S.; Tetrahedron Lett. 46 (2005) 44, 7483-7485; Dep. Biol. Chem., Fac. Sci., Okayama Univ. Sci., Ridai, Okayama 700, Japan; Eng.) -Mais 08-194