Stereochemical applications of deuterium magnetic resonance. I. The prins reaction of trans-β-deuteros·tyrene

We have investigated the Prins‐reaction of formaldehyde on several cyclic (poly) olefins. The nature (100 and 300 MHz NMR studies; table II) and yields of the resulting 1,3‐dioxanic compounds have been carefully assessed (Table I). The results indicate that most previous claims are to be taken only as general rules, with many exceptions however. Thus, a wide variety in stereospecificity of the primary reaction must be accepted, leading to syn and anti (diaxial) and even trans (diequatorial) addition routes. It seems acceptable that only protonated polymeric formaldehyde oligomers may rationalize such a broad spectrum of possibilities.

show abstract

NMR experiments on acetals. Part 48 the prins‐reaction on cyclic (poly) olefins and the characterization of resulting 1, 3‐dioxanes

Coryn

Anteunis

1974

Bulletin des Soc Chimique

View full text Add to dashboard Cite

show abstract

Deuterium magnetic resonance, applications in chemistry, physics and biology

Mantsch

Saitô

Smith

1977

Progress in Nuclear Magnetic Resonance Spectroscopy

281

104

View full text Add to dashboard Cite

Polymeric ionic liquid as novel catalyst for the Prins reaction

Jin

Kang

et al. 2020

Arabian Journal of Chemistry

View full text Add to dashboard Cite

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

hi@scite.ai

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Stereochemical applications of deuterium magnetic resonance. I. The prins reaction of trans-β-deuteros·tyrene

Cited by 6 publications

References 10 publications

NMR experiments on acetals. Part 48 the prins‐reaction on cyclic (poly) olefins and the characterization of resulting 1, 3‐dioxanes

NMR experiments on acetals. Part 48 the prins‐reaction on cyclic (poly) olefins and the characterization of resulting 1, 3‐dioxanes

Deuterium magnetic resonance, applications in chemistry, physics and biology

Polymeric ionic liquid as novel catalyst for the Prins reaction

Contact Info

Product

Resources

About