Stepwise reactions of two N–CH2CN or two N–CH2C(NH)OMe groups attached to macrocyclic copper(II) complexes: Preparation of homo- and hetero-di-N-functionalized macrocyclic complexes

Reduction of N-Cyanomethyl Groups on a Macrocyclic Nickel(II) Complex Using Sodium Borohydride: Synthesis of a Complex Bearing Two N-(2-Aminoethyl) Pendant Arms

“…[7][8][9][10][11][12][13][14] )](ClO 4 ) 4 2H 2 O4DMSO suitable for X-ray study were grown from water-DMSO solution. Intensity data were collected on a Rigaku R-AXIS RAPID II-S diffractometer.…”

Synthesis and Characterization of New Mono-N-functionalized Tetraaza Macrocyclic Nickel(II) and Copper(II) Complexes

“…[16][17][18][19][20][21][22][23] ): 3320 (ν N-H ) and 2230 (ν C≡N ). Although mass spectrum of the product shows a main peak corresponding to L 11 , it also contains a small amount of uncharacterized by-product(s).…”

Synthesis and Characterization of New Tetraaza Macrocycles Bearing Two or Four N-Methoxyethyl Pendant Arms and Their Copper(II) and/or Nickel(II) Complexes

“…[1][2][3][4][5][6][7][8][9][10][11][12][13] In general, coordination geometry and chemical properties of such compounds are strongly influenced by the nature and number of the functional groups.…”