The Bayer process holds an exclusive status for alumina extraction, but
a massive amount of caustic “red mud” waste is generated. In this
work, three oxalate reagents: potassium hydrogen oxalate
(KHCO), potassium tetraoxalate
(KHCO·HCO),
and oxalic acid (HCO)
were investigated for the Al and Fe extraction process from NIST SRM 600
– Australian Darling range bauxite ore. More than 90% of Al and Fe was
extracted into the aqueous phase in less than 2 h with 0.50 M
CO for all three
reagents. The Fe and Al can be selectively precipitated by hydrolyzing
the aqueous phase. By acidifying the Al and Fe free filtrate, 80% of
the CO can be
precipitated as
KHCO·HCO.
Greater than 90% of the aqueous acid can also be recycled using a
cation exchange resin. The proposed closed-loop process is an
energy-efficient, cost-effective, environmentally-friendly route for
extracting Al and Fe from bauxite ore.